Helium Is Hard to Replace

(construction-physics.com)

101 points | by JumpCrisscross 3 hours ago ago

53 comments

  • sixhobbits 2 hours ago

    I really enjoyed this oddlots podcast episode that covered similar points and had a lot of "wat" moments for me, including the US selling off its strategic helium reserves at a loss because politicians labeled it "party baloon reserve", and how long it takes to produce naturally and how hard it is to find, process and transport.

    https://m.youtube.com/watch?v=bjc6MgUY0BE

    • amelius 17 minutes ago

      I'm guessing you can find a supply of helium near the top of the atmosphere :)

      • dmitrygr 8 minutes ago

        Turns out -- no, it permanently escapes to space with the help of the solar wind

    • parineum 2 hours ago

      Part of the reason there's a shortage is because the US was the main supplier. There was no market incentive for anyone to invest into helium extraction.

      It'd be like if the US used it's strategic oil reserve to supply the US with oil at a low price at all times.

      A strategic reserve isn't supposed to be used as a supply. The existence of a strategic reserve shouldn't have an effect on the supply of helium except in an emergency. The fact that selling the helium reserve could create a shortage should tell you that it wasn't being used as a reserve but as a supply.

      The US was, essentially, artificial subsidizing the price of helium. What's happening now is that people are actually paying the real price of helium.

      • marcosdumay an hour ago

        The US government decided (maybe correctly, IDK) some years ago that their strategic helium reserves were too high (and thus expensive).

        There were several announcements, a lot of discussion, and a long process before they started selling it. It was also a temporary action, with a well known end-date (that TBH, I never looked at). It had a known and constant small pressure over investments, it wasn't something that destabilized a market.

      • actionfromafar an hour ago

        Exactly right. We may yet find out what happens when someone sells the strategic oil reserve.

        • dave78 32 minutes ago

          About half of the strategic petroleum reserve was sold off in 2022.

        • rootusrootus an hour ago

          Despite all the online rhetoric, and the popularity of mis-naming political movements, sometimes I think the people who hate America the most and want it to fail are Americans themselves.

          • senderista an hour ago

            I think that's broadly true: both sides want America to fail when the other side is in power in order to prove they're right.

  • Aboutplants an hour ago

    I’m not really worried about any potential helium shortage. We are actually really good at extracting it, the problem is purely economics and as soon as prices get to the point where investment is warranted then there will continue to be adequate supplies. The main issue right now is the proper demand increase forecasts do not align with potential investments costs and helium extraction investment does just not make much economic sense given current forecast Helium costs.

    • vlovich123 28 minutes ago

      If demand keeps growing (as it has been), we've got ~40-60 years of "cheap" reserves left. As helium prices start to increase, you've got price shocks down the supply chain.

      There's about 40-70 billion cubic meters of economically recoverable (assuming future technology development + price increases). The complete total upper end of known geological reserves is ~60-100 billion cubic meters - that's about correct in terms of order of magnitude even if we find new deposits.

      Current consumption is 180 million cubic meters/year. At a growth of 3%, you've got 80-140 years before we run out. At 5% growth it's 50-90 years.

      Saying "I'm not worried about it" is true in the myopically selfish "I personally won't have to care about it". It's conceivable that your children will be dealing with it and definitely grandchildren in a very real existentially meaningful way.

      • cheschire 20 minutes ago

        > myopically selfish

        A standard western personality trait I’ve been confronted with repeatedly over the last… hmm. Well that got depressing real quick.

      • dtech 9 minutes ago

        It's very hard if not impossible to do predictions over century timescales. How relevant are 1926 resource problems to today? If you wrote your comment in 1926 you would be talking about rubber, fertilizer, coal, wood or oil, and 4 out of those 5 are mostly solved today.

        At those timescales, mining the moon or Jupiter for helium might be realistic, so the limits of earth are no longer upper bounds.

  • throw0101d 2 hours ago
  • nradov an hour ago

    For diving, there has been some experimental use of hydrogen as a partial replacement for helium in breathing gas mixtures. This obviously increases the risk of fires and the physiological effects aren't fully understood. But it might eventually be used in commercial, military, and exploration diving for those cases where we need to send humans really deep and using an atmospheric suit isn't an option. Regular sport divers will probably never breathe hydrogen.

    https://indepthmag.com/hydrogen-dreamin/

    • snek_case an hour ago

      For divers, we really should be focusing on building better underwater drones. Remove the risk to human life entirely. You don't need AI either, just a remote-controlled machine with a cable that goes up to the surface. I know there is some loss in dexterity with current robot arms, but building more dexterous system seems like it's not an impossible task.

      • nradov 44 minutes ago

        ROVs have already reduced the demand for commercial divers on some types of work. But it's going to take decades (if ever) until they're able to do the full range of human tasks. Some construction work has to be done essentially by feel in near-zero visibility so using an ROV for that would require advanced force feedback mechanisms, maybe imaging sonar and other sensors. Not necessarily impossible, but extraordinarily difficult and extremely expensive with current technology.

        For sport and exploration divers, going there yourself is kind of the whole point. I'm not interested in watching a video feed from an underwater drone.

  • cineticdaffodil 27 minutes ago

    So how hard would it be for elon to build a gas raffinery sattelite that captures helium while skimming the top layer of the atmosphere, dropping filled canisters by parachute?

    • bigyabai 20 minutes ago

      You'd need investors willing to pay $50,000\kg of helium, for one.

    • DonHopkins 19 minutes ago

      So how hard would it be for elon to treat his own daughter with the respect that every human being deserves and every parent owes to their children, and stop viciously abusing and attacking and deadnaming and misgendering her online in front of billions of people?

      Maybe he should first prove that he has a shred of humanity and decency and isn't the worst parent in the world, before attempting to harvest helium from the upper atmosphere at whatever the cost.

  • LorenDB 2 hours ago

    Is there any way to actually produce helium other than nuclear fusion? I would assume not, but I'm not an expert in this field.

    • nradov 2 hours ago

      Helium is produced naturally by radioactive decay underground. There is no way to artificially produce it in useful quantities.

      But we can capture more of it from natural gas wells. Today much helium is just vented off and wasted at wellheads. As the price rises it makes sense to invest in cryogenic helium capture equipment for more wells.

    • adrianN 2 hours ago

      It can form during radioactive decay of uranium and thorium.

      • wat10000 2 hours ago

        And that's where all of our helium actually comes from. Any radioactive decay that emits alpha particles generates helium, since alpha particles are just helium nuclei. When that happens underground, the helium can get trapped. It tends to get trapped in the same places that natural gas gets trapped, so natural gas extraction often encounters helium as well.

        Similar to oil and gas (although a completely different mechanism), it takes deep time to accumulate, but can be extracted much, much faster. So although new helium is being generated underground all the time, we can still run out in a practical sense.

    • sixhobbits 2 hours ago

      It's also formed similarly to oil over millions of years underground if I understand correctly so can be a byproduct of natural gas mining.

      • daemonologist 2 hours ago

        It's often found alongside natural gas because the rock structures that can trap methane can also trap other gasses, but the original source is different - thermal decomposition of organic matter for natural gas and radioactive decay, mostly of uranium and thorium, for helium.

        I agree that the "accumulation over millions of years" is similar (and similarly a potential problem if we burn through all that accumulation).

      • Sharlin an hour ago

        Which is exactly 100% of Earth's helium. Every single helium atom we use is a result of alpha decay, as a very good approximation there isn't any primordial or stellar helium on or in Earth.

    • jmyeet 2 hours ago

      Terrestial helium isn't produced by nuclear fusion. It's produced by nuclear decay. As you may know, you get alpha, beta and gamma radiation from decay. Gamma rays are just energetic photos. You typically need thick lead and/or concrete to shield you from them. Beta radiation is high energy electrons. A thin sheet of steel will shield you from those.

      And lastly we have alpha radiation, which is just a Helium nucleus. A sheet of paper will generally block alpha radiation.

      Some materials are really strong alpha emitters. A good example is Polonium-210 where almost all of its energy from decay is in the form of alpha radiation. This is why Po-210 is so lethal when ingested, which has been used for that purpose [1].

      But this means if you produce a lump of Polonium-210, it's basically radiating Helium. The source of almost all of the Earth's Helium is from uranium and thorium decay.

      [1]: https://en.wikipedia.org/wiki/Poisoning_of_Alexander_Litvine...

      • onraglanroad an hour ago

        > Gamma rays are just energetic photos

        They are indeed. The average planet busting Gamma Ray Burst is just a Vogon trying to "get the whole family in".

    • CamperBob2 2 hours ago

      If you have something that emits a lot of alpha particles as it decays, you could surround it with a source of electrons, I suppose. The details would have to be left as an exercise, and I doubt you'd get enough helium to be very useful unless you were dealing with large amounts of ridiculously-radioactive substances.

      Same with fusion. Due to the implications of E=mc^2, fusion yields a lot of energy and a uselessly-small amount of matter. There don't seem to be many good ways to get a lot of helium besides either waiting millions of years for it to show up naturally, or carefully recycling what we already have.

      • kergonath an hour ago

        > you could surround it with a source of electrons, I suppose

        Water would be the best for this. The cross-section is good and water can ionise easily. But yeah, you would not get a lot of it.

    • cubefox an hour ago

      The reason helium can't be produced chemically (like hydrogen can be produced e.g. from water) is that there are no natural chemical compounds which contain helium. That's because it doesn't form those compounds in the first place, since it's a noble gas.

    • nsxwolf 2 hours ago

      Atmospheric extraction on Earth would require massive amounts of energy and infrastructure.

      Gas giant atmosphere extraction sounds very far future

  • llm_nerd 2 hours ago

    Recently had to deal with radon in a basement, leading me to a fun side trek of learning about uranium decay (it has been a lot of years since chemistry classes).

    When you hear about alpha decay of radioactive materials, that is the matter spitting off a highly ionized helium nucleus, freshly birthed into this world. That He nucleus rapidly steals electrons from matter, which is how it can be dangerous to human cells if ingested.

    All of that helium underground is the result of alpha decay, and a single uranium-238 element will birth 8 helium atoms as it transitions through a series of metals and one gas (radon), then finally finding stability as Pb206. U235 will birth 7, becoming Pb207.

    Anyways, found that fascinating. It's just happenstance that helium often gets blocked exiting the crust by the same sort of structures that block natural gas from escaping, and they are an odd-couple sharing little in common.

    One other fun fact -- radon only has a half life of 3.8 days. Uranium becomes thorium becomes radium, then radon where it has an average 3.8 days to seep out of the Earth and into our basements, where it then becomes radioactive metals that attach to dust, get breathed in (or eaten) and present dangers. In the scale of things, crazy. Chemistry is fascinating.

    • 867-5309 2 hours ago

      > That He atom rapidly steals electrons from matter

      tfa:

      > Thanks to its filled outer electron shell, it is inert, and won’t react with other materials

      • llm_nerd 2 hours ago

        The particle that is emitted from an alpha decay isn't actually called a He atom (I edited my root comment so this isn't misleading, apologies) -- I was being loose with terminology -- though it has the right number of protons and neutrons. It's called an alpha particle. Once it steals two electrons -- it carries a +2 charge and is extremely successfully at slicing electrons off of other molecules it comes across -- it is then considered the helium that we know and love, and is now stable with the properties we know.

        And by stealing those electrons from other molecules it sets off other chemical reactions, which in things like DNA is highly suboptimal. This all generally happens at the birth of the He atom, presuming it isn't in deep space or something with no electrons to cleave from neighbours, and is only an instantaneous state.

        • JumpCrisscross an hour ago

          > *particle that is emitted from an alpha decay isn't actually called a He atom”

          “Because they are identical to helium nuclei, they are also sometimes written as He2+…” [1].

          [1] https://en.wikipedia.org/wiki/Alpha_particle

          • onraglanroad 44 minutes ago

            You should really have posed that as a "I don't know anything about this so I'm confused" question.

          • kergonath an hour ago

            He2+ is not a helium ion, which is very reactive. It’s not a helium atom, which is inert.

            • llm_nerd 42 minutes ago

              I think there's an accidental "not" in that first sentence. Though I'm pretty sure Jump above was just noting the nomenclature (He<sup>2+</sup>) which is interesting.

        • DonHopkins 8 minutes ago

            He has risen,
            He has risen,
            He has risen,
            Helium is alive.
      • wat10000 2 hours ago

        Because it rapidly steals electrons, it becomes inert quickly. Helium you find lying around will be inert. Helium that has just shot out from the radioactive decay of an unstable atom will not be inert.

        • chii 2 hours ago

          I would imagine that an alpha particle would still be inert in the sense that it won't cause chemical reactions with other molecules.

          • kergonath an hour ago

            Stealing electrons is a chemical reaction.

  • Invictus0 2 hours ago

    Fun fact, helium was discovered on the Sun nearly 30 years before it was found on earth.

    • CamperBob2 2 hours ago

      Hence the origin of the name!

  • KalandaDev 2 hours ago

    For a second I thought this was about Helium browser :(

  • jmyeet 2 hours ago

    The US used to have a massive Strategic Helium Reserve [1]. Starting in the 1990s, Congress passed a law to sell down the reserve. This flooded the market with cheap Helium (yay, party balloons?) because the mandated pricing just didn't make any sense.

    10-20 years ago there was a lot of talk about how this was foolish because it was depleting and squandering an unrenewable resource. But the thinking has shifted on that because it's an inevitable byproduct of natural gas production.

    Now natural gas itself is limited but you can still get Helium from alpha decay of radioactive elements. Some elements are particularly strong alpha emitters (eg Polonium-210, Radium-223). They're basiclaly producing Helium constantly.

    Helium is a known issue in various industries. The article notes (correctly) that MRI Helium use is decreasing because of the rise of so-called "Helium free" or "Helium light" MRI technology.

    But there are short term supply issues. As noted, Qatar produces ~30% of the world's Helium currently. And that can (and has) been disrupted by recent events.

    Lithography is a particularly important consumer of Helium for superconducting magnets. That demand is rising with probably no end in sight. Lithography itself is on the cutting edge of technology and engineering so seems harder to replace. I mean, EUV lithography is basically magic.

    [1]: https://en.wikipedia.org/wiki/National_Helium_Reserve

    • nradov an hour ago

      Shutting down the National Helium Reserve seemed like a good idea at the time. It was originally established when airships were considered essential for national security, largely for maritime patrol. But blimps and dirigibles fell out of favor for most military missions and there wasn't much demand for other uses, so it was politically hard to justify wasting tax dollars to maintain a reserve.

    • cubefox an hour ago

      The article briefly touches on insufficient recycling. Though it's not clear for which applications helium recycling is technically/economically feasible and for which it isn't.

  • nisegami 2 hours ago

    I recently began wondering if a planet's helium supply could be the 'great filter'. As in, if a civilization could stall out due to not having access to enough helium to product the technology to access off-world helium.