138 comments

  • sktrdie 5 hours ago

    Apart from food packaging, one great way to easily ingest plastic is to use synthetic clothing. Just a basic rubbing of a synthetic sleeve on your nose causes thousands of polyester particles to release in thin air, readily breathable.

    Not just clothing, but also bedding is a huge issue. With pillows, mattresses and towels mostly made of synthetic fibers.

    My usual instinct is: try rubbing the synthetic material; if it releases thousands of particles in thin air, stay away from it

    • hammock a few seconds ago

      Are there phthalates in polyester clothing?

    • ericmcer 4 hours ago

      Clothing industry has somehow gotten by unscathed during all the environmental awareness that has spread in the past 20 years. I am pretty sure clothes are the #1 cause of the microplastics that have inundated the ocean and our water supply.

      We have been heavily pushed to drive less, recycle more, and use less water, but I have not seen messaging about not buying new clothes you don't need.

      • jabl 43 minutes ago

        > Clothing industry has somehow gotten by unscathed during all the environmental awareness that has spread in the past 20 years. I am pretty sure clothes are the #1 cause of the microplastics that have inundated the ocean and our water supply.

        Surprise surprise, it has actually been studied. One recent review article of the field:

        https://www.science.org/doi/10.1126/science.adl2746

        From figure 2b) we can see that while microplastics from synthetic fibres are certainly an issue, they are far from #1. Dwarfed by tires, paint, and macroplastics (large plastic pieces thrown away slowly grinding down into microplastics e.g. by wave action).

      • jerlam 3 hours ago

        France passed a law back in 2020 to require new washing machines to have a microplastics filter by 2025:

        https://www.europarl.europa.eu/doceo/document/E-9-2020-00137...

        It has also begun to subsidize the clothing repair industry:

        https://www.cnn.com/2023/07/13/business/france-shoe-clothing...

        • klipt 2 hours ago

          Maybe we should subsidize plastic-free fibers instead. Cotton, hemp, wool...

          • echelon an hour ago

            Though I wouldn't expect the average consumer to take a full course in organic chemistry, perhaps we can train the public to see benzene rings.

            Counting electron delocalization density and reactivity can be a rule of thumb for DNA mutation.

            Basically a, "Does your chemical look like this? Maybe consume less of it." infographic.

          • bilbo0s 2 hours ago

            You still have massive downsides to new cotton or wool clothes. There's just less of the micro plastic downside. Clothing is just a place where we take a massive hit on everything from carbon output to micro plastics.

            Another issue is clothing repair. I think the clothing repair thing is kind of brilliant. But for clothing repair to work you would need to disincentivize buying new clothes. Which subsidizing clothing would work against.

            • JumpCrisscross 2 hours ago

              > for clothing repair to work you would need to disincentivize buying new clothes

              Why? I repair clothes. I also like buying new ones. In between I ruin and lose items, or find that I no longer wish to wear them for purely stylistic reasons.

            • pkaye 2 hours ago

              Higher quality clothes like in the past might be nice. Stuff seems to fall apart so quickly these days.

              • ffujdefvjg 2 hours ago

                Older clothes weren't just made better, people also took care of them better. Partly because of cost, but also culture -- fewer changes in fashion trends with slower and more local communication, cheap labor to launder your clothes by hand (which puts much less wear on the garment). Also a culture of repairing and mending (also easier to do this when you have fewer things to occupy your free time).

                • jabl 33 minutes ago

                  Yes. But really, it was much worse in many ways. A 100 years ago, say, the people doing clothes repair for a living were desperately poor, and often being single women they often had to resort to prostitution to feed themselves as the income from repairing clothes simply wasn't enough.

                  I do think that from an environmental standpoint we should repair and recycle clothes a lot more than we do, but lets not romanticize the past. The small clothes repair businesses disappeared for a reason as living standards improved. Furthermore, today factory production of clothes is incredibly efficient and tends to be done in low-income countries, further making it even harder to restart some kind of clothes repair industry in high-income countries.

      • schiffern 4 hours ago

        The problem isn't really "buying new clothes," since most of the microplastics are released in the laundry. Sewage treatment plants aren't designed to remove them, so they get released with the discharge water. It can also clog up septic leachfields.

        They do make purpose-built products to filter microplastic lint from laundry[1][2], but a more hacker approach is to just search for "pool filter."

        I wish they made comparable products for the dryer.

        [1] https://www.filtrol.net/

        [2] https://planetcare.org/

        • onlypassingthru 2 hours ago

          > I wish they made comparable products for the dryer.

          Isn't that just the lint filter? Every dryer I've seen has one.

      • rustcleaner 9 minutes ago

        With luck, maybe some new nudity tolerance movements can be fomented. :^D

      • haccount 4 hours ago

        There's an entire big and celebrated business sector that spends every working hour taking intact plastic products and grinds then into fine shreds, a process likely to contribute more than a fair share to microplastic dissemination. Maybe worth investigating, a good candidate for more microplastic release than the clothing industry.

        Name of that business sector? Plastics recycling.

        • arcticbull 3 hours ago

          Plastics recycling also kinda barely exists. Only 5% of plastic in the US is recycled, the whole thing was a greenwashing operation by oil companies to encourage additional consumption. Realistically putting the plastic deep underground back from whence the hydrocarbons came is not a bad sequestration strategy.

          https://www.npr.org/2020/09/11/897692090/how-big-oil-misled-...

          • brnt 3 hours ago

            The US is at the back of the pack though, in Europe some countries recycle more than half of plastic.

            • pkaye 2 hours ago

              Do they recycle or just burn it for energy?

              • greenavocado 2 hours ago

                Countries like Sweden, Denmark, and Switzerland incinerated 50-80% of their plastic waste. Germany incinerated around 50%. Countries in Eastern and Southern Europe generally had lower incineration rates and higher landfill rates. Approximately 42% of plastic waste in Europe was being incinerated in waste-to-energy facilities.

            • redwall_hp 2 hours ago

              Same for aluminum, which is highly recyclable. A ridiculous amount of it ends up in landfills for no reason other than people can't be fucked.

              Plastic recycling is just another American "we tried nothing and are out of ideas." Much of the lack of recycling for plastics, when it comes to bottles, isn't some grand conspiracy so much as people just throwing bottles in the trash or on the side of the road, because:

              * There aren't omnipresent recycling bins to go alongside trash cans.

              * There aren't local programs for recycling pick up.

              * Some people can't be bothered and the government isn't punching them in the face, as it should.

              Only a half dozen states have a can/bottle deposit, even. Each state should be required to have deposits and municipal recycling pickup in any city of appreciable size, and heavy penalties for littering, or all sorts of federal funding should be withheld.

      • throwaway19972 2 hours ago

        > We have been heavily pushed to drive less, recycle more, and use less water, but I have not seen messaging about not buying new clothes you don't need.

        It's there if you follow the right people on social media.

        Campaigns that center around personal responsibility, however, aren't ever going to work, and there's obvious reasons why people are willing to pay to push this narrative but not the buying fewer clothes one (at least here in the US).

      • smm11 an hour ago

        Vintage clothing stores are a great resource to combat this. It's sad how expensive many are, but you can also try thrift stores for clothes.

      • andai 2 hours ago

        >not buying new clothes you don't need

        Pretty sure I don't need the ones made of microplastics!

    • buildbot 5 hours ago

      I hate how normalized this is. Breathing in a difficult to break down plastic dust is not something that seems healthy.

      • potato3732842 4 hours ago

        Nitpick:

        All else being equal you're generally safer being exposed to stable things that don't break down than unstable things that happily react with all sorts of things (and tend to meddle with the chemical processes required for life).

        If you get to choose between breathing tires and milk jugs pick the milk jugs every time.

        • Terr_ 2 hours ago

          > All else being equal you're generally safer being exposed to stable things that don't break down than unstable things that happily react with all sorts of things

          There's a similar paradox in nuclear radiation. (Sometimes expressed with a puzzle about differently radioactive cookies and what to do with each.)

          Gamma rays are scary because it takes a lot of lead shielding to even slow them down... but that also means that they aren't stopping to interact with things--like yourself--as they travel.

          Alpha particles seem relatively safe because they don't travel far and are blocked by your skin... But that means they're doing something to that skin, and luckily for you any damage is being dealt to already-dead cells on the outside.

          But if you had to put one of them inside your body, it's quite possible the gamma ray emitter would be the safer option, simply because more of its energy would escape harmlessly.

          • nordsieck 2 hours ago

            > But if you had to put one of them inside your body, it's quite possible the gamma ray emitter would be the safer option, simply because more of its energy would escape harmlessly.

            That's definitely the case with Polonium-210. Even though it emits alpha particles, it's very dangerous to ingest.

        • mschuster91 4 hours ago

          > All else being equal you're generally safer being exposed to stable things that don't break down than unstable things that happily react with all sorts of things

          Unless the other thing is asbestos or generally any kind of mineral/anorganic material - pneumoconiosis [1] is nasty in all its variants. There is no mechanism at all for your body to break down or expel anorganic contaminants in your lungs.

          > If you get to choose between breathing tires and milk jugs pick the milk jugs every time.

          Well, plastic, glass or metal, no matter what the jugs are made of, they'll hurt your lungs just like the tire dust will.

          [1] https://en.wikipedia.org/wiki/Pneumoconiosis

          • webstrand 4 hours ago

            > There is no mechanism at all

            I think that's somewhat misleading, the lung has a mucus layer and cilia to move particles caught in the mucus up and out. But I'll agree that it's not a completely robust system. Anything that gets past or can't be moved by the mucus layer is going to be a problem, especially particles that can't be broken down by the macrophages.

          • potato3732842 4 hours ago

            >Unless the other thing is asbestos or generally any kind of mineral/anorganic material - pneumoconiosis [1] is nasty in all its variants. There is no mechanism at all for your body to break down or expel anorganic contaminants in your lungs.

            Yup. I was thinking of heading off comments like yours by mentioning silicosis or lead poisoning but didn't want to clutter up a simple clarification.

            Anyway, still mostly safer than "happy to react with things" compounds which is why people like you get to make comments about it here and now vs it simply being a thing everyone has accepted is not good to breath for hundreds of years (like certain wood dusts)

        • amanaplanacanal 4 hours ago

          Aren't they both plastic?

          • klodolph 4 hours ago

            There are plastics in the tire, but the exterior bulk of the tire is rubber, which is not plastic.

            • arcticbull 3 hours ago

              Yep, rubbers are generally the class of elastomers.

              Natural rubber is poly-cis-isoprene, synthetic rubbers are a mix of petroleum-derived polymers.

        • sitkack 3 hours ago

          > All else being equal

          This premise only exists in a synthetic hypothetical universe.

          • Dilettante_ an hour ago

            Would it be too snarky for HN to reply "Yes, that is indeed how hypothethicals work"?

        • brnt 3 hours ago

          I doubt this. Sure, reactants aren't good, but impossible to biologically break down neither. Causing havoc and bioacumulating seem to be two ends of a spectrum, where you want to be in the middle. Stuff that safely and easily broken down.

      • kulahan an hour ago

        Nobody is going around purposely breathing in plastic dust, there's been dust everywhere forever, and breathing in dust is a natural and unavoidable part of life.

        What, exactly, do you think is normalized here? That people wear clothing? That people didn't throw out every polyester fiber the moment somebody said plastic can break down into small pieces? That people aren't freaking out over a danger that we know roughly nothing about so far?

        People really need to stop finding excuses to freak out over things.

    • afh1 3 hours ago

      Hum, almost all of my t-shirts are 100% cotton, or at least that's what the label says. I use mostly the same clothes from 15 years ago so maybe synthetic is more common nowadays? I think the only t-shirts I own that are not 100% cotton are those I've got for free on things like marathons and hackathons. Does it contain phthalate? I have no idea, there is no label saying what they are made of. Probably polyester. Does it have phthalates in any meaningful concentration? This review says basically that "it varies a lot" and "needs further study". https://www.sciencedirect.com/science/article/pii/S138266892...

      • resoluteteeth 42 minutes ago

        Interestingly Table 4 in that link shows "Plain weave cotton" and "polyster" having similar levels of phthalates.

        I don't think phtalates are needed as plasticizers in polyster, so I guess they are coming from the dyes or something else used to treat the fabrics, meaning that the choice of cotton or polyster may not matter for phthalates specifically?

      • brookside 2 hours ago

        I recall the cotton tees of my youth being stiff and terrible-feeling.

        • DontchaKnowit 2 hours ago

          100% cotton can be waaay comfier than poly blends. Just depends on the weave/wash

    • zw7 4 hours ago

      I think about this every time I clean out the dryer lint filter and a plume of lint dust comes off of it. I try to avoid breathing it in but it’s likely some is making it into my airways.

      • faitswulff 4 hours ago

        Since getting used to them during Covid, I've continued wearing masks for situations just like this.

        • hedgehog 3 hours ago

          I manage that by using a vacuum to clean my lint filter but folding seems to release a lot of dust so I do that next to an air filter.

      • jerlam 3 hours ago

        The lint is also the residue from your clothes being worn away. If you can, consider not using the dryer at all, especially for synthetic clothing which air dry quickly compared to cotton.

      • mike_ivanov 4 hours ago

        Besides containing microplastics, the dryer lint is also radioactive

        https://news.ycombinator.com/item?id=35990858

    • Tade0 2 hours ago

      My mattress cover is like that, as it's made from polyester. When I pull it from the dryer it produces an invisible, but irritating cloud of particles.

      All that while most of the shavings accumulate in the lint collector, so it could have been even worse.

    • JumpCrisscross 2 hours ago

      > a basic rubbing of a synthetic sleeve on your nose causes thousands of polyester particles to release in thin air, readily breathable

      Source?

    • mschuster91 4 hours ago

      > Not just clothing, but also bedding is a huge issue. With pillows, mattresses and towels mostly made of synthetic fibers.

      Preach. I vacuum my bedsheets every day because my cats are insane shedders and I'd otherwise get breaded with cat fur, but the vacuum is full with so much what is clearly not cat fur...

    • 29athrowaway 4 hours ago

      And plastic shower liners.

    • binarymax 4 hours ago

      It’s frustrating how hard it is now to buy pure cotton or <gasp> wool, from a store. Even if it’s 3% synthetic it’s still not what I’m looking for.

      • mandmandam 4 hours ago

        Yep. Specifically, why are 100% cotton socks so ridiculously hard to find now?

        It used to be that they were a little more expensive - now you need to go online to find them.

        'Fun' fact - the average brain has about 7 grams of microplastic [0] in it now, up 50% from 2016. At that rate...

        SEVEN FUCKING GRAMS. Guys this is beyond stupid.

        Even if plastic were totally inert, as I've heard people insist with certainty (where are they getting these ideas!), 7 grams of plastic in your brain is terrifying.

        0 - https://edition.cnn.com/2024/08/23/health/plastics-in-brain-...

        • Terr_ 2 hours ago

          I wonder if anyone's done a study for similar-but-natural compounds... Does lignin accumulate? Could we find a whole bunch of it in the brains of carpenters?

        • roncesvalles 3 hours ago

          >Specifically, why are 100% cotton socks so ridiculously hard to find now?

          My theory is that it's because of Amazon reviews. For most socks on Amazon, there will be at least one reviewer posting pictures of how their socks got holes after a few days of wearing. These reviewers are ridiculous and seem to have sandpaper for flooring, sweat corrosive acid, or deliberately wear down these socks just to post the review. I've bought many different socks from Amazon and none of them get holes even after years of wearing them.

          Anyway, I think that seems to have spooked socks manufacturers.

        • layer8 3 hours ago

          > Even if plastic were totally inert […], 7 grams of plastic in your brain is terrifying.

          Why do you find that terrifying, if it’s inert?

          To the downvoters: This is a genuine question.

          • timr an hour ago

            Also, don't worry, there's not actually 7 grams. The study that suggested that was ridiculously bad.

            When you extrapolate 100,000-fold from uncalibrated micro-scale experiments, you get insane results, but the typical internet reader doesn't get past the abstract of the paper and instantly activates panic mode, instead of questioning the insanity.

          • abeppu 2 hours ago

            Even if they're _chemically_ inert, physical accumulation of particles of foreign matter in your brain might be causing problems. When it gets inside of cells, is it in the way of any processes? When it's between cells, does it trigger scarring? Do the particles clog capillaries? And because the study referenced was only able to find these particles via autopsies, if microplastics in your brain were causing health issues for you, you probably would never find out or be able to mitigate.

          • beowulfey 2 hours ago

            Even things that are chemically inert can cause problems in our bodies. Silica is similarly chemically inert, but silicosis is a devastating disease.

          • lo_zamoyski 30 minutes ago

            Because chemical effects are not the only undesirable effects something can have. E.g., mechanical, electrical.

            In any case, in one study [0], "researchers looked at 12 brain samples from people who had died with dementia, including Alzheimer’s disease. These brains contained up to 10 times more plastic by weight than healthy samples." Another [1] found "nanoplastics accelerate the aggregation of β-amyloid peptides" and that they exacerbate "the neurotoxicity induced by low-concentration peptides".

            [0] https://www.theguardian.com/environment/article/2024/aug/21/...

            [1] https://www.sciencedirect.com/science/article/abs/pii/S03043...

          • brnt 3 hours ago

            The simple answer is that it isn't supposed be there. The more interesting one is: how much would you say is too much? Would a kilo of microplastics towards the end of your life do it?

            • layer8 3 hours ago

              When it has adverse effects (and no benefits), then of course it’s too much. But GP seemed to be saying they find it terrifying even assuming no adverse effects, which I found curious.

              A huge number of people have implements in their bodies (in their teeth, most often), and much more than seven grams of “foreign stuff” in their stomach and intestines all the time, so that by itself doesn’t seem anything to be terrified of.

              • klipt 2 hours ago

                > In Italy, researchers followed 312 patients who had fatty deposits, or plaques, removed from their carotid artery. Almost six in 10 had microplastics, and these people fared worse than those who did not: Over the next 34 months, they were 2.1 times as likely to experience a heart attack or stroke, or die.

                https://www.theguardian.com/environment/article/2024/aug/21/...

              • marmadukester39 2 hours ago

                it’s more the unknown effects. It’s not clear this stuff is actually inert.

              • throwway120385 2 hours ago

                Would you be so blase if it were 7 grams of diesel exhaust or coal particulates instead?

    • brnt 3 hours ago

      I often wonder about carpet or seats and couches. Also made of all manner of synthetic fabrics. Even besides the effects of living in the same space flame retardants slowly gas off over the decades, we rarely deep clean any of this, so when we sit down a cloud of craps wafts up into our lungs.

      I prefer noncarpets, but hard seating of course not.

  • whatshisface 4 hours ago

    The story of phthalates really highlights the drinking from the fume hood aspects of our commercial norms. Phthalates are designed to squeeze between hydrophobic polymers such that their bulk mechanical properties are changed, while remaining chemically inert and not subject to breakdown. The question of what this would do in the human body, which is full of polymers with very sensitively evolved mechanical properties, was obvious - yet it was not asked in a funded capacity until we had been letting it accumulate in our kids for decades. The position of our institutions on this is a clear case of preferring not to know.

    • Nahtnah 32 minutes ago

      This whole thread is a great example of an interesting phenomenon... whenever people talk about this people come out of the woodwork to nitpick the details of whoever is criticizing the wonton use of likely poisonous compounds. Theyll argue things like this about the details of the exact likely bioactivity of the compound, or go on about how its impossible to have modern society without poisoning everything in a huge perfect enemy of the good argument.

      Like, go drink from a cup of pthalates if youre so ok with it being in your brain, balls, ovaries, etc. No ones arguing we need to ban plastics, but maybe coating the world in single use water bottles without considering the effects is suboptimal. Shouldnt the onus be on proving its safe before spreading it everywhere, rather than proving its dangerous?

      https://ethz.ch/en/news-and-events/eth-news/news/2021/06/wor...

      Theyll call me extreme/ignorant/naive, but maybe a society where we have to poison ourselves to sustain "growth" isnt worth sustaining.

      Not to mention the constant alarm bells about rising GI cancers in younger people. "OH BuT YOU HAVNEnT staTIstiCALLY prOved A cAusAL AssOCiaTION".

      • timr 27 minutes ago

        I'm not nitpicking the parent. The parent comment is just wrong, full stop. You should not listen to them.

        They have an incorrect notion of what a phthalate is (usually a slightly greasy ester or an alcohol), how polar/hydrophopic they are (mixed; generally ampiphilic), and whether or not they tend to bioaccumulate (in general, they do not).

        Your broader point is well-taken, however, but not in the way you intended: chemistry does not reward a shallow understanding. The details matter a lot.

        • Nahtnah 24 minutes ago

          You're arguing as if you understand all the side effects of the biochemistry on the biology. None of us do. Theyre correct about one thing: its probably not good for you.

          But sure, you might be more right on the basics of the biochemistry.

          I guess I'm just frustrated about the state of the world - im not a degrowth person I just want a better balance.

          There seems to be plenty of evidence for, for example, their role in endocrine disruption.

          • timr 20 minutes ago

            At no point did I claim they were "good for you". I'm just saying that the OP is not making a valid argument.

            • Nahtnah 13 minutes ago

              Sure, but I didnt claim he made a valid argument either. What I am claiming is when someone says things like

              "The question of what this would do in the human body, which is full of polymers with very sensitively evolved mechanical properties, was obvious - yet it was not asked in a funded capacity until we had been letting it accumulate in our kids for decades"

              which the article I linked supports, people come out of the woodwork to argue we need "more evidence/an exact biochemical pathway" when we dont have the understanding/technology to actually do that.

      • foxglacier 19 minutes ago

        You're assuming we're all being poisoned. We might not be, and clearly if we are, it's not a huge effect because we're still not obviously more diseasous than before. It could even be that the benefits of these chemicals on civilization outweigh the health costs so we're better off using them.

        • Nahtnah 18 minutes ago

          You're assuming were not all being poisoned, lol. Did you even read what I wrote.

          There's plenty of evidence we're increasingly fucking with our bodies, again see the rising rates of cancer in youth. Yes, there are likely many causes for that. You'd have to be criminally negligent to argue a class of chemicals like phthalates is in the clear. Yes, the details are complicated. Yes, the dose makes the poison. Yes.

          I believe we're smart enough to find a way to have/eat out cake, but smart people are arguing in this classic way about details that miss the main point people should care about, downplaying the issue in a way that laypeople cant understand the nuance of. So we keep following the $$$ and likely poisoning ourselves.

    • timr an hour ago

      You can't just say "squeeze between hydrophobic polymers", as if that's a single thing, and therefore any such "hydrophobic polymer" will be vulnerable to a phthalate.

      In particular, DNA is not hydrophobic -- it's an extremely polar environment. The known DNA/RNA intercalating chemicals are also very polar (at least, in critical selected locations). For example, Ethidium Bromide:

      https://en.wikipedia.org/wiki/Ethidium_bromide

      Point being: assuming that the paper in the headline is true (which I do not assume, but I digress), your theory of the mechanism is probably wrong, and therefore misleading.

      Edit: having now looked at the paper, they're discussing one specific chemical (bezyl butyl phthalate) which is actually quite polar. It's also an ester, and trivially broken down by common enzymes into a number of different child compounds, any of which could be individually responsible for the claimed effects. Biochemistry is complex.

      • whatshisface an hour ago

        It gets into hydrophobic binding sites, and accumulates in lipids.

        > Aromatic compounds, aliphatic hydrocarbons, and halogens are the hydrophobic parts of ligand PAEs. Hydrophobic contact is caused by the spatial proximity of the non-polar amino acid side chains and the hydrophobic substituents on the ligand PAE molecules. Water molecules are released from the hydrophobic region upon hydrophobic contact, and the unconstrained water molecules released can participate in the energy-favorable hydrogen bonding interactions, which enhance the overall binding affinity of the ligand [37,38,39]. Therefore, the hydrophobic interactions between ligands and receptors affect the ability of PAEs to bind to hormone proteins and influence the ability of PAEs to bind to DNA response elements.

        https://pmc.ncbi.nlm.nih.gov/articles/PMC10488033/

        • timr an hour ago

          The paper is about DNA mutation. DNA is not a hydrophobic binding site. It doesn't interact with hydrophobic binding sites. Moreover, the chemical studied in this particular paper is not particularly hydrophobic.

          Your theory is wrong, at least in this case. Also, this paper says the opposite of what you think it says:

          > based on the three-dimensional potential energy surface information, it was discovered that the hydrophobic, steric, and electrostatic fields of PAEs significantly influence their endocrine disruption effects on humans.

          They're saying that hydrophobic effects matter, but non-hydrophobic effects also matter. So everything matters.

          FWIW, the paper is not particularly worth citing. Someone made an ML model that said what any competent chemist could tell you by looking at a phthalate.

          • whatshisface an hour ago

            Who said DNA was hydrophobic? I'm sorry, but we're not disagreeing. Phtalates are very lithophilic and that's a major mechanism of their accumulation in the body.

            If phtalates were highly polar, they wouldn't be soluble in plastic. That means they're going to bind to fat tissue and non-polar receptors.

            >the chemical studied in this particular paper [...]

            Also, the paper didn't study "a chemical," it covered about 30.

            • timr an hour ago

              I'm telling you that you're overgeneralizing based on incorrect information. The paper being discussed here directly refutes your hypothesis of action, because it's about a particular chemical that is known to be metabolized, causing downstream effects in an extremely polar molecule (DNA).

              Generally, "pthalates" are not a thing, but rather a whole bunch of different things (some are hydrophobic, some are not), and many of them are metabolized by the human body, so they don't actually accumulate. You have to be more specific.

              https://pubmed.ncbi.nlm.nih.gov/17604388/

              > If phtalates were highly polar, they wouldn't be soluble in plastic.

              Setting aside "highly polar", which is not specific, you are wrong. Many/most pthalates are far from what chemists consider "hydrophobic", and are in fact esters, alcolhols and acids.

              > Also, the paper didn't study "a chemical," it covered about 30.

              The paper in the OP was about one molecule: BBP.

              • whatshisface 37 minutes ago

                >Generally, "pthalates" are not a thing, but rather a whole bunch of different things (some are hydrophobic, some are not), and many of them are metabolized by the human body, so they don't actually accumulate. You have to be more specific.

                I am being specific enough to be talking about the hydrophobic pthalates that do accumulate in the human body. If I was talking about the other ones that claim would be trivially wrong... when the popular media says cyanide is dangerous, they're talking about the dangerous molecules with R-CN, not the safe ones.

                • timr 34 minutes ago

                  > I am being specific enough to be talking about the hydrophobic pthalates that do accumulate in the human body.

                  They're all amphiphilic, to some degree. That's how they work. It's also common to the chemical group that they break down quickly, because they tend to be esters and alcohols. Any phthalates that bioaccumulate would be the exception, not the rule.

                  https://www.sciencedirect.com/science/article/abs/pii/S14384....

    • fuzzfactor an hour ago

      >preferring not to know.

      I think this does have some ongoing influence on why more detailed analysis of common chemicals is not required.

      From what I can tell, it looks like phthalates started with excess coal tar which contained tonnes of a solid waxy aromatic hydrocarbon called naphthalene that nobody probably had much of a way to monetize for quite some time.

      Plenty of money was surely being made in other ways so regardless of the accounting methods, the surplus ends up being a no-cost item. When there are tonnes of an unutilized resource like this the full-scale effort would turn every tonne into something useful, and all it has to do is be the least bit useful and the least bit worth money for it look pretty good on paper. Plus the longer it builds up without having a good way to get rid of it can make a difference. Especially if one of the physical properties of the asset has something to do with combustibility and/or toxicity.

      This gives extreme financial leverage compared to comparable chemical processes where a major raw material has a nominal cost, or even an attractive cost.

      Anyway, naphthalene was an early source of cheap phthalic acids & anhydrides.

      Also some oil fields have enough naphthalene content for it to be accumulated in the bigger refineries along with other waxy hydrocarbons which are processed in abundance.

      Plus to meet increasing demand phthalic anhydride can also be made from ortho-xylene which many more refineries are commonly processing a stream of. This may not be zero-cost raw material, but it is still a hydrocarbon which is in bulk and easy to add value to if you're going to do something other than burn it for fuel.

      In the 1980's the phthalate I would see the most of was "di-octyl phthalate", known as DOP. It was mostly di-(2-ethylhexyl) phthalate since the "octanol" that formed the diester was usually 2-ethylhexanol, not much n-octanol involved.

      The 2-EH itself was some nasty-smelling stuff, one drop on your foot and you would have to leave your shoes outside when you got home. It was a byproduct of butanol & isobutanol manufacture, which themselves are relatively clean solvents. The 2-EH was clarified but it is a low-volatility solvent that doesn't dry up very fast, and stinks so bad it is not an ideal paint ingredient. There was no published laboratory testing procedure but I did do some pioneering chromatography anyway and there was a rich array of minor byproducts which are still most likely not fully identified chemically yet.

      So 2-EH is another low-cost item but not much higher viscosity than the butanols.

      Esterifying to combine with the phthalic and you get the compound DOP, the syrupy liquid used as a plasticizer that doesn't dry up much faster than the plastic solids themselves, and imparts the increased flexibility desired by the processor.

      I wouldn't be surprised if there are some minor impurities in the DOP that trace back to the 2-EH raw material, which could be much more potent endocrine disruptors than the known plasticizer chemical itself. The statistical possibility is based on the number and variety of unidentified minor constituents, the way that very small amounts of hormones have very outsized effects, and the correlations that have been seen which incriminate the plasticizer and seem to show some connection.

      Plus, after a few short years being a leading analyst of 2-EH and DOP, one day some highly purified 2-EH became available in "research grade", purchased it to serve as reference material, and it turned out to be relatively odor-free ! It was the 2-ethylhexyl aldehyde content that made it smell so bold. So I have known something was up for a very long time but still don't have all the details I would want.

      Now if there is some minor component other than the known plasticizer bulk chemical itself which is causing disruption, and in-vivo work is being done on the highly purified reference material in order to evaluate the target plasticizer itself in the absence of as many unknowns as possible I'm not so sure the findings would apply as much in the real would as I would like.

      At the beginning, phthalates were not optimized to serve as plasticizers.

      They just happened to not fail at the task.

      Got more popular, and non-surplus alternative sources of raw materials for plasticizing will break ground to meet the demand once the more-attractively-priced "chemical waste" has all been spoken for.

      Something like a playbook that predates the plastic age.

  • b800h 3 hours ago

    I hate to be the one to say this (especially as phthalates are horrible) but it needs a suffix:

    "......in worms."

    • calibas an hour ago

      "The study also showed that C. elegans metabolizes BBP in the same way as mammals, and is impacted at similar BBP levels that occur in humans, suggesting that C. elegans is an effective model for studying the impacts on people."

  • broof 3 hours ago

    https://www.consumerreports.org/health/food-contaminants/the...

    CR showing how much of it is in our food. What’s crazy is how unpredictable it is, some have little, and other very similar products have 100x the amount. As a consumer I have little ability to control this.

  • ssijak 5 hours ago

    Why are we not considering banning plastics in most household items?

    • arcticbull 5 hours ago

      Only certain plastics contain phthalates.

      There aren't any in polypropylene plastic, polyethylene plastic or polycarbonates.

      I'm sympathetic, less plastic is probably good - it does have to be a well thought through change. If the change reduces safety, or if it gets manufacturers to switch to a worse risk profile product, we could be net worse off.

      • nyanpasu64 4 hours ago

        Sadly I found a study at https://pmc.ncbi.nlm.nih.gov/articles/PMC3222987/ saying that many polypropylene polyethylene products release estrogenic chemicals (IDK if it's the same as phthalate) likely from additives, including when bent/deformed. And polycarbonates are infamously made of polymerized BPA and similar chemicals (usually endocrine disruptors).

        • arcticbull 3 hours ago

          Thanks for sharing the study. I will say the made-from argument is less compelling since table salt is made from sodium (explosive) and chlorine (chemical warfare agent) and yet it's pretty yummy. So long as it doesn't degrade, that's not super problematic. However the study I will read.

    • krunck 4 hours ago

      "They [phthalates] are used primarily to soften polyvinyl chloride (PVC). " [1]

      PVC is used in water pipes, bottles, packaging films, blister packs, cling wraps, and seals on metal lids.[2]

      [1] https://en.wikipedia.org/wiki/Phthalates [2] https://en.wikipedia.org/wiki/Polyvinyl_chloride#Application...

      • afh1 3 hours ago

        >PVC water pipes

        This is the most relevant one IMO. You can buy glass cups and jars, it doesn't matter if the water you put into them comes through PVC pipes! Even if you buy BPA-free phthalate-free bottled water, I think it's safe to assume that at one point that water went through several meters of PVC pipes to get to that bottle!

        PVC water pipes must be ubiquitous nowadays, and are certainly better than the older copper alternative, which in turn is better than the older lead alternative!

        Maybe the next step is special PVC for water piping. Until then I guess we're better than we have ever been, water piping-wise.

        • mrob 3 hours ago

          Water pipes are made from rigid, unplasticized PVC. It's only flexible PVC (e.g. cable insulation) that contains plasticizers.

          • afh1 3 hours ago

            Well, great, then!

            • morpheos137 2 hours ago

              Yeah as long as you're not chewing or extension cords you should be good.

              The most common water pipe in new construction is cross linked polyethylene. XLPE. It is stable, inert, and contains no plasticizers. PVC is often used for sewage drain pipes. Like the parent said it is the rigid crystalline kind typically containing minimal plasticizers tightly bound within the crystal matrix.

        • hedgehog 3 hours ago

          It depends. Leaching from cold water passing through a pipe for a few seconds is a lot different from a water bottle that might be in a backpack or warm car most of a day.

      • CodeWriter23 4 hours ago

        Also quite commonly used as a fragrance enhancer.

        • jackyinger 4 hours ago

          That’s horrifying. But thanks for pointing that out, now I’ve got a real reason to dislike artificial odors (“air fresheners”)

      • MichaelZuo 3 hours ago

        PVC is also commonly used in 3D printing, with very pungent fumes.

        • Filligree 3 hours ago

          Professional 3D printing, perhaps. I imagine it's a common engineering plastic.

          Home 3D printing fortunately uses mostly PLA, which is biodegradable. Though I'm unsure how degradable it'd be inside your lungs.

    • Ekaros 4 hours ago

      Because they are very useful. And in general have great properties. You known weight, resiliency, price and so on.

    • dylan604 4 hours ago

      Look at all of the bottles/containers in your bath/shower. Would you really want glass in a wet slippery area? Metal containers?

      • peterb0yd 4 hours ago

        I use bar soaps for everything. Ethique is an amazing brand. https://ethique.com/

      • ssijak 3 hours ago

        yes, I would. thick glass is great and cant break easily if it is smaller container. there is also stainless steel and other materials.

        plastic was invented 100 years ago. people did just fine in the house without it.

        • morpheos137 2 hours ago

          People also survived without antibiotics and electricity in past. Electricity generation is a far bigger environmental load than plastic. By your logic we should revert to burning candles. Even windmills and solar panels are made from toxic chemicals. Everything in life has its tradeoffs. It is not responsible to use a one sided mass hysteria to impose a lower standard of living on people when it is not clear what the quantifiable harm the technological innovation that is plastics is to justify doing so. Many things are toxic in the right dose but the dose makes the poison. Making policy without considering tradeoffs is the road to Idiocracy and watering plants with Brawndo.

      • TeeMassive 4 hours ago

        You mean like perfume and cosmetics? Sturdy glass with carpets near the bathroom sink and the shower will do the trick. I'll take a few cuts through my life over cancer and chronic diseases.

        • mrob 4 hours ago

          >carpets near the bathroom sink and the shower

          Now every spillage is a potential mold growth problem, which is also bad to inhale.

      • Dig1t 4 hours ago

        I mean, you could make a simple and cheap bottle out of aluminum probably? We had shampoo before the widespread usage of plastic bottles, though you are right that they used to come in glass. Perhaps we could use that fancy unbreakable soviet glass.

        Sounds like a good business idea actually..

        Edit: Actually thinking about it, that really is a good business idea. If anyone wants to build that business with me, email me at the address in my bio.

        • dylan604 2 hours ago

          You just have to convince the vast majority of people that the extra expense of the container is worth it to them.

          I have taken a very unscientific poll, and a very few number of people would want glass containers. You have to realize that people commenting on HN are not the mass public. The polls I've done were just asking during specific skincare product related conversations. The vast majority were onboard for paraben/phthalate free products made from plant based ingredients, but the no plastic issue was not something people felt strongly about at all.

        • maeil 3 hours ago

          These exist for cosmetics[1], though the pump is still plastic. Would work fine for other shower products too.

          [1] https://www.amazon.com/Calvin-Klein-one-Skin-Moisturizer/dp/...

    • diffeomorphism 2 hours ago

      We should also ban plants while we are at it, since there are only a few letters of difference.

      In other words: Banning certain types of plastics makes sense and we do that all the time. Banning "plastics" is about as sensible as banning dihydrogenmonoxide.

    • mistrial9 4 hours ago

      see "Green Chemistry" in the USA about 20 years ago.. science was well-developed.. also "Body Burden" search term.. largely stone-walled at the politics level.

      "Product liability is a third-rail in American politics" yes

    • bpodgursky 5 hours ago

      Because it would drive prices of basic household goods up 400% and make low and middle income families vastly poorer.

      I'm all for pushing back on chemicals wherever possible, especially in food packaging, but let's be real.

      • alyandon 5 hours ago

        I try to avoid reheating things in plastic containers. It's about the only thing I can think of I can do as a consumer to reduce the risk of chemicals leeching into the food.

      • vundercind 4 hours ago

        I think furniture and carpet would get it worse than most stuff. The alternatives to plastic (largely glass) in other cases are more like 20-50% more expensive, but furniture? Carpet? Solid wood and wool, leather—god, I dunno what you’d even use for cushion fill that’d last anywhere near as long. Those are closer to 400% the price of synthetic stuff. Or more.

        • jabl 17 minutes ago

          > I dunno what you’d even use for cushion fill that’d last anywhere near as long. Those are closer to 400% the price of synthetic stuff. Or more.

          AFAIU natural latex is an alternative to the ubiquitous polyurethane foam, and lasts longer. Quite pricey though.

        • maxwell 4 hours ago

          Pine. Oak. Jute. Bamboo.

          • reissbaker 4 hours ago

            FYI, bamboo is usually actually:

            1. Some actual bamboo that has been processed to remove starches and sugars

            2. Mixed with incredible amounts of chemical glues (some of which include BPA)

            Most bamboo products are at least as suspicious to me as plastic.

          • cyberax 3 hours ago

            All the bamboo flooring products are engineered (in other words). Oak is great for flooring, but it's impractically heavy for the furniture.

      • CodeWriter23 4 hours ago

        > would drive prices of basic household goods up 400%

        Glass is nominally more expensive and works. Our go-to food storage is mason jars. $12/dozen, probably cheaper by volume than the plastic crap on the shelves at Target or Walmart.

        • haccount 3 hours ago

          A bottle of wine by mass is ballpark 50% glass and 50% wine. A one liter glass jar of olives around 300 grams of glass.

          So it's not merely packaging cost but also about convenience of shipping it around.

          That said we still manage to ship both of those all over the world despite the unfavorable mass and relative sensitivity of their packaging.

          The jar of olives however have plastic liner in the jar lid, so you're not escaping plastics anyway. The solution as I see it is to use the right plastics in the right way and ensure proper disposal of the waste.

          • morpheos137 2 hours ago

            Wine and olives also cost more than milk and eggs. You can package milk in glass bottle 5 percent of the weight of the product made at thousands of degrees from burning fossil fuels or you can package it in an inert HDPE container, that is processed at several hundred degrees and weighs say 0.5% of the product contained within. lighter packaging means less fuel burned to ship it. Lower processing temperatures means less fuel burned to make it. Ethylene polymerized into plastic for milk jugs doesn't end up in the air as CO2. Plastic feed stocks directly compete with fuel feed stocks. The less fuel we need to burn to ship things the more carbon is kept out of the atmosphere and the more carbon made into plastic that is stable when buried for thousands of years the less ends up in the air. You can make a lighter foam egg carton for less cost, that better protects the eggs than a paper one. Paper is no more a natural material than plastic. The manufacturing process releases hydrogen sulfide, contaminates water and when the paper rots the toxic dyes in ink printed on it is unbound and free to leach into the environment. Paper cups are coated with persistent waxed and plastics that migrate once the cup that supported them is gone. White paper products are bleached and brown paper is produced with harmful chemicals including even flame retardants at times. What is cheapest, lightest and most stable is usually also the most environmentally friendly thing.

      • milch 4 hours ago

        There are "bulk" stores that have no packaging and you fill up what you need into reusable containers that you either buy or bring yourself. They generally have common bulk items like flour but also lots of options for typical grocery store fare. The prices at those stores generally aren't 400% of what they are at a regular grocery store, and if they are higher I'm sure a large part is that this is a niche kind of store rather than how everyone gets their groceries.

        That's obviously not the whole supply chain, and I'm sure many goods still arrive at that kind of store in plastic, but these tend to be run by the types that avoid plastic anyway so whatever they can get in reusable packaging I'm sure they are getting wrapped in something other than plastic. Anyway, if plastic is going to be used, the exposure from a single 100lbs bag of something that you refill into a container is probably vastly lower than from 100 individually wrapped 1lbs bags

        • mrob 4 hours ago

          That kind of thing only works in a high trust society. Given the choice, I'm not going to buy food from bulk bins where some stranger could have contaminated them, whether by malice or incompetence.

      • mschuster91 4 hours ago

        > I'm all for pushing back on chemicals wherever possible, especially in food packaging, but let's be real.

        The devil is that food that comes pre-packed under vacuum or inert atmosphere in plastics lasts much, much longer than food that gets stored in anything else - including tin cans by the way, they're all lined with plastics because acidic food would otherwise literally eat away the can.

      • TeeMassive 4 hours ago

        Jars can be refilled. I think things would actually get cheaper.

  • foxglacier 34 minutes ago

    This is misleading. "at levels similar to those detected in humans, [...] egg cells with the wrong number of chromosomes."

    So where are all these people with the wrong number of chromosomes? They should be everywhere. Maybe all this damage ends up leading to no human growing from the egg, so they're never born but again where are all the infertile women? It should be nearly everyone! It's either written to deceive or it's obviously wrong.

  • lasermike026 3 hours ago

    No one cares. The people profit from this don't care. Virtually everyone who buys these products doesn't care either. If you care and you want to do something about it get on the next spaceship, leave the earth and abandon this unintelligent human species.

    • manmal 30 minutes ago

      That spaceship‘s interior, functional space outfit, and most equipment will of course also consist of various plastics.

  • Dig1t 4 hours ago

    Reminder that the FDA denied a petition last year to ban these chemicals in food packaging.

    https://www.fda.gov/food/hfp-constituent-updates/fda-respond...

    There is already a mountain of research showing that phthalates are endocrine disruptors and cause developmental defects. The FDA knows this and is doing nothing.

  • morpheos137 3 hours ago

    The blind irrational hatred of "plastics" is bordering on a religion or mass hysteria.

    HN is supposed to be a forum of educated, rational people capable of critical thought. Here are some basic facts.

    1. Plastic is often presented in the media as some kind of monolithic hazardous compound where it is not. There are different kinds of plastic. Alternatives are usually economically and environmentally inferior.

    2. The most common types of plastic for consumer applications are polyethylene and polypropylene, followed by polyvinyl chloride and polystyrene. PE and PP are biologically and chemically inert. The same reason why they don't break down is the reason why they are harmless. Polystyrene derived from a naturally occuring compound styrene found in some plants and can and does breakdown under attack of UV light, acids, microorganisms. All three PE, PP, and PS are most commonly manufactured without harmful additives. Only PVC uses significant quantities of plasticizers some of which are harmful. Unless you are chewing on your shower curtain you have little to worry about.

    3. At least several hundred billion tons of commodity plastics have been mass produced over the last 70 years with little to no quantified, attributable environmental damage from these plastics. Most microplastic is essentially inert dust that is no different from other organic or inorganic dust such as pollen or clay. Plastics are not allergens because they are non reactive and do not stimulate an immune response. It is very likely that blood of animals contains plastic molecules along with thousands of other molecules in trace quantities doing no more harm than natural silt in a river system.

    4.The fact that commodity plastics do not readily rot or degrade is a good thing. Petroleum carbon made into stable plastic and buried in a landfill is kept out of the atmosphere.

    5. Plastic items are less energy demanding to recycle and produce in the first place because of lower thermal processing requirements than glass, metal or wood.

    6. Lignin in wood is a natural plastic.

    7. Most of the macro plastics in the ocean comes from Asia and the fishing industry. In the west it is buried in a landfill where it helpfully sequesters carbon.

    8. Plastic items are often lighter to ship also consuming less energy that way versus alternatives.

    9. Most microplastics in the ocean are from synthetic fibers and tire abrasion. I have yet to see a non handwaving study that these actually result in significant environmental harm. Maybe we should research more durable tire materials. Perversely electric vehicles wear tires quicker than ICE vehicles due to a more aggressive torque curve. Cotton has to be planted (diesel tractor), sprayed with fertilizers and pesticides, picked (diesel), spun, woven, etc. just because it's natural doesn't mean it's better for the environment at mass scale. This true of other things too like glass, metal, paper, etc.

    10. People should stop irresponsibly hating on plastics when the alternatives are worse.

    This neo Luddite Puritanism is just dumb and unscientific.

    I challenge anyone to rebut my assertions with hard facts that quantify to supposed damage plastic does versus what alternatives would do.

    • throwway120385 2 hours ago

      We're all responding to an article about how plasticizers used in certain plastics to make them all more flexible can damage DNA in some organisms. Why do you consider that empirical study to be new Luddite Puritanism? And if the plasticizer can leach out of plastics, which has been shown in numerous studies over the years, why do you consider them inert?

      It's not enough to assert, loudly, that you are right and we are all wrong and everything is fine let's all go back inside and let the chemists keep doing what they're doing. You have to explain also why PE and PP never under any circumstances ever contain any plasticizers.

      Regarding plastics and microplastics in the oceans, I've seen tons of pictures of dead birds that after autopsy have filled their crops with broken plastic pieces instead of food. This is not good, and having all of our sea birds die is not an insignificant environmental harm.

      So hand-waiving that away doesn't change the fact that introducing plastics have caused new and exciting forms of harm in our biosphere.

    • sktrdie 42 minutes ago

      I agree with many of the points, but how do they relate with the article at hand?

    • tirant 2 hours ago

      Electric vehicles have extremely precise traction control due to the nature of their motors so even with higher torque they keep traction much better than their ICE counterparts.

      EVs are also heavy and might wear tires quicker in braking situations though.

  • ugh123 5 hours ago

    Also used in sex toys

    • mschuster91 4 hours ago

      These are mostly made of silicon based plastics, glass or metal and by definition don't have that much exposure time to the user's body.

      • ugh123 an hour ago

        Of course i'm not referring to toys made from glass or metal.

        > Prior material analyses of sex toys like those characterized here revealed phthalate concentrations in most tested products at concentrations ranging from 24–60% by weight [11, 14, 15]. In addition, there is growing concern over human exposure to micro-and nano-plastics. The translocation and biouptake of nano-sized particles is now well established [16]. Human exposure to nanoplastics and the potential for enhanced release of plastic additives are of potential concern.

        https://pmc.ncbi.nlm.nih.gov/articles/PMC10034881/#:~:text=P....